伊津野 真一

J-GLOBALへ         更新日: 17/08/02 11:08
 
アバター
研究者氏名
伊津野 真一
 
イツノ シンイチ
URL
http://ens.tut.ac.jp/chiral/
所属
豊橋技術科学大学
部署
工学部 環境・生命工学系 分子機能化学分野
職名
教授
学位
工学博士(東京工業大学), 工学修士(東京工業大学)

研究分野

 
 

受賞

 
1987年
手島記念研究奨励賞(手島工業教育資金団)
 
1996年
有機合成化学協会「研究企画賞」
 

論文

 
Shinichi Itsuno, Shotaro Takahashi
ChemCatChem   9 385-388   2017年2月   [査読有り]
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimA chiral main-chain polyamide containing an (R,R)-1,2-diphenylethylenediamine monotoluenesulfonamide (TsDPEN) repeating unit was prepared. Polycondensation of dicarboxylic acid dichloride with the c...
Synthesis of Chiral Polyamides Containing an (R,R)-1,2-Diphenylethylenediamine Monosulfonamide Structure and Their Application to Asymmetric Transfer Hydrogenation Catalysis
Shinichi Itsuno, Shotaro Takahashi
ChemCatChem      2017年
Polyesters Containing Chiral Imidazolidinone Salts in Polymer Main Chain: Heterogeneous Organocatalysts for Asymmetric Diels-Alder Reaction
Naoki Haraguchi, Liem Nguyen Tanh and Shinichi Itsuno
ChemCatChem      2017年
Shinichi Itsuno
ACS Symposium Series   1236 241-274   2016年9月   [査読有り][招待有り]
© 2016 American Chemical Society.Boron hydrides, comprising Lewis acidic borane derivatives and basic metal borohydride derivatives, are versatile reducing agents that have wide applications in chemistry, both in the laboratory and on an industria...
Shohei Takata, Yuta Endo, Mohammad Shahid Ullah, Shinichi Itsuno
RSC Advances   6(76) 72300-72305   2016年8月   [査読有り]
© 2016 The Royal Society of Chemistry.The Mizoroki-Heck polymerization of cinchona-based sulfonamide dimers and aromatic diiodides was investigated in the presence of a palladium catalyst, to obtain chiral polymers in high yields. An iodobenzenesu...
Mitsuaki Narita, Masakuni Narita, Yasuko Itsuno, Shinichi Itsuno
{ACS} Omega   1(6) 1355   2016年12月   [査読有り]
Highly active polymeric organocatalyst: Chiral ionic polymers prepared from 10, 11‐didehydrogenated cinchonidinium salt
Md. Mehadi Hassan, Naoki Haraguchi, Shinichi Itsuno
J. Polym. Sci. Part A: Polym. Chem.      2016年
Md Mehadi Hassan, Naoki Haraguchi, Shinichi Itsuno
Journal of Polymer Science, Part A: Polymer Chemistry   54(5) 621-627   2016年3月   [査読有り]
© 2015 Wiley Periodicals, Inc.Since few examples of 10,11-didehydrogenated (3-ethynyl) cinchona alkaloids have been utilized as organocatalysts in asymmetric reaction, we synthesized 10,11-didehydrogenated cinchonidine. The 3-vinyl group of cincho...
Boron Hydride Reduction
Shinichi Itsuno
ACS Symposium Series      2016年
Synthesis of cinchona alkaloid sulfonamide polymers as sustainable catalysts for the enantioselective desymmetrization of cyclic anhydrides
Shohei Takata, Yuta Endo, Md. Shahid Ullah, Shinichi Itsuno
RSC Advanced      2016年
Itsuno S.
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry   74(7) 710-719   2016年   [査読有り]
Protein Folding Structures: Formation of Folding Structures Based on Probability Theory
Mitsuaki Narita, Masakuni Narita, Yasuko Itsuno, Shinichi Itsuno
ACS Omega      2016年
Shinichi Itsuno, Tatsuaki Oonami, Nagisa Takenaka, Naoki Haraguchi
Advanced Synthesis and Catalysis   357(18) 3995-4002   2015年12月   [査読有り]
© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.In this study, enantiopure imidazolidinones containing two hydroxyphenyl groups were synthesized, and the Williamson synthesis of the chiral bisphenols thus prepared with dihalides afforded polyeth...
Shinichi Itsuno
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry   74 710-719   2016年7月   [査読有り]
Novel synthesis of chiral polymers containing catalytic active sites is described. Precise control of the chiral polymer structure gives specific chiral microenvironment suitable for an asymmetric catalysis. These polymeric chiral catalysts often ...
Shinichi Itsuno, Md Mehadi Hassan
RSC Advances   4(94) 52023-52043   2014年10月   [査読有り]
© the Partner Organisations 2014.Polymer immobilization of chiral catalysts has progressed extensively over the past years. Recent intensive development of chiral organocatalysts resulted in the identification of numerous highly active catalysts, ...
Polymer-immobilized chiral catalysts
伊津野 真一
RSC Advances   4 52023-52043   2014年11月   [査読有り]
Shinichi Itsuno, Shunya Yamamoto, Shohei Takata
Tetrahedron Letters   55 6117-6120   2014年10月
© 2014 Elsevier Ltd. All rights reserved.Various kinds of 4-(bromomethyl)benzenesulfonamides were prepared as quaternization reagent of cinchonidine. Cinchonidinium salts obtained from the quaternization of cinchonidine with 4-(bromomethyl)benzene...
Md Robiul Islam, Parbhej Ahamed, Naoki Haraguchi, Shinichi Itsuno
Tetrahedron Asymmetry   25 1309-1315   2014年10月
© 2014 Elsevier Ltd. All rights reserved.A thiol-ene reaction of dithiol and two equivalents of cinchonidine afforded a thioetherified cinchonidine dimer. The dimer was treated with benzyl bromide to give a quaternary ammonium dimer. An ion exchan...
Shinichi Itsuno, Yosuke Hashimoto, Naoki Haraguchi
Journal of Polymer Science, Part A: Polymer Chemistry      2014年8月
This article details the enantioselective catalytic performance of crosslinked, polymer immobilized, Ir-based, chiral complexes for transfer hydrogenation of cyclic imines to chiral amines. Polymerization of the achiral vinyl monomer, divinylbenze...
Md Masud Parvez, Naoki Haraguchi, Shinichi Itsuno
Macromolecules   47 1922-1928   2014年3月
To facilitate the asymmetric catalysis process, we designed novel polymeric chiral catalysts. Since quaternary ammonium salts of cinchona alkaloid derivatives show efficient catalytic activity in various asymmetric transformations, we have synthes...
Haruki Sugie, Yosuke Hashimoto, Naoki Haraguchi, Shinichi Itsuno
Journal of Organometallic Chemistry   751 711-716   2014年2月
Crosslinked polymers containing chiral N-sulfonylated diamine (TsDPEN) structure were synthesized by radical polymerization of chiral N 1-(4-vinylbenzenesulfonyl)-1,2-diphenylethylene-1,2-diamine, divinylbenzene and achiral vinyl monomer. The poly...
Shinichi Itsuno, Yosuke Hashimoto, Naoki Haraguchi
Journal of Polymer Science, Part A: Polymer Chemistry   52 3037-3044   2014年1月
© 2014 Wiley Periodicals, Inc.This article details the enantioselective catalytic performance of crosslinked, polymer immobilized, Ir-based, chiral complexes for transfer hydrogenation of cyclic imines to chiral amines. Polymerization of the achir...
Polymer Catalysts
Shinichi Itsuno
Encyclopedia of Polymeric Nanomaterials      2014年
Shinichi Itsuno
Kobunshi   63 170-171   2014年1月
Quaternary ammonium salts of cinchona alkaloid show excellent catalytic activity in various asymmetric organic reactions. In order to immobilize these chiral catalysts in the main-chain of polymers, cinchona alkaloid dimers were polymerized with a...
Synthesis of Polymer-Immobilized TsDPEN Ligand and its Application in Asymmetric Transfer Hydrogenation of Cyclic Sulfonimine
Haruki Sugie, Yosuke Hashimoto, Naoki Haraguchi, Shinichi Itsuno
J. Organomet. Chem.      2014年
Synthesis of Cinchona Alkaloid-Derived Chiral Polymers by Mizoroki-Heck Polymerization and Their Application to Asymmetric Catalysis
Md. Masud Parvez, N. Haraguchi, Shinichi Itsuno
Macromolecules      2014年
Synthesis of Chiral Iridium Complexes Immobilized on Amphiphilic Polymers and their Application to Asymmetric Catalysis
Shinichi Itsuno, Yosuke Hashimoto, Haruki Sugie, and Naoki Haraguchi
J. Polym. Sci. Part A: Polym. Chem      2014年
Synthesis of chiral polymers containing thioetherified cinchonidinium repeating units and their application to asymmetric catalysis
Md. Robiul Islam, Parbhej Ahamed, Naoki Haraguchi, Shinichi Itsuno
Tetrahedron: Asymmetry      2014年
Polymer Immobilized Chiral Catalysts
Shinichi Itsuno, Md. Mehadi Hassan
RSC Advanced      2014年
Itsuno S.
Kobunshi   63(3) 170-171   2014年   [査読有り]
Synthesis of chiral quaternary ammonium polymers for asymmetric organicatalysis application
Parbhej Ahamed, Md. Aminul Haque, Mikiya Ishimoto, Md. Masud Parvez, Naoki Haraguchi, and Shinichi Itsuno
Tetrahedron      2013年
Parbhej Ahamed, Md Aminul Haque, Mikiya Ishimoto, Md Masud Parvez, Naoki Haraguchi, Shinichi Itsuno
Tetrahedron   69 3978-3983   2013年5月
Main-chain chiral quaternary ammonium polymers have been synthesized using cinchonidine or 10,11-dihydrocinchonidine as a chiral source. Since the quinuclidine moiety of cinchonidine is easily quaternized with halide to form cinchonidinium salt, t...
Ikuhide Fujisawa, Noriko Harima, Kenji Takagi, Shuichi Hiraoka, Mitsuhiko Shionoya, Kazutaka Murayama, Shinichi Itsuno, Ryo Kato, Katsuyuki Aoki
Bulletin of the Chemical Society of Japan   85 1037-1039   2012年9月
X-ray analyses of two calix[4]pyrogallolarene complexes with DL-proline have shown that they form hostguest-like 1:1 complexes in which the pyrrolidine ring of proline is incorporated into the bowl-shaped cavity of calix[4]pyrogallolarene through ...
Masud Parvez, Abdus Salam, Naoki Haraguchi, Shinichi Itsuno
Journal of the Chinese Chemical Society   59 815-821   2012年7月
Repeated reaction between chiral quaternary ammonium dimer and disodium disulfonate gave the ionic polymer, which contains chiral quaternary ammonium sulfonate structure as a repeating unit. This chiral ionic polymer showed an excellent catalytic ...
Naoki Haraguchi, Parbhej Ahamed, Masud Parvez, Shinichi Itsuno
Molecules   17(6) 7569-7583   2012年6月   [査読有り]
Main-chain chiral quaternary ammonium polymers were successfully synthesized by the quaternization polymerization of cinchonidine dimer with dihalides. The polymerization occurred smoothly under optimized conditions to give novel type of main-chai...
Naoki Haraguchi, Hitomi Kiyono, Yu Takemura, Shinichi Itsuno
Chemical Communications   48(33) 4011-4013   2012年4月   [査読有り]
Main-chain polymers of chiral imidazolidinone were successfully synthesized by reaction of chiral imidazolidinone dimers with disulfonic acid. Chiral imidazolidinones were incorporated into the main-chain of the polymer by ionic bonding. These pol...
Synthesis of Chiral Ionic Polymers Containing Quaternary Ammonium Sulfonate Structure and their Catalytic Activity in Asymmetric Alkylation
Md. Masud Parvez, Md. Abdus Salam, Naoki Haraguchi, and Shinichi Itsuno
J. Chinese Chem. Soc.      2012年
Md Masud Parvez, Naoki Haraguchi, Shinichi Itsuno
Organic and Biomolecular Chemistry   10(14) 2870-2877   2012年4月   [査読有り]
Repeated reaction between a chiral quaternary ammonium dimer and disodium disulfonate gave a chiral ionic polymer, which showed excellent catalytic activity in the asymmetric benzylation of N-diphenylmethylene glycine tert-butyl ester. © The Royal...
Polymer design for asymmetric catalyst immobilization
Shinichi Itsuno, Yosuke Hashimoto, Haruki Sugie, and Naoki Haraguchi
Porous polymer-based systems (EUPOC 2012)      2012年
Synthesis of main-chain polymers for asymmetric organocatalysis application
Naoki Haraguchi, Hitomi Kiyono, Md. Masud Parvez, Parbhej Ahamed, and Shinichi Itsuno
Chirality 2012      2012年
Synthesis of Main-chain Chiral Quaternary Ammonium Polymers for Asymmetric Catalysis Using Quaternization Polymerization
Naoki Haraguchi, Parbhej Ahamed, Md. Masud Parvez, and Shinichi Itsuno
Molecules      2012年
Molecular Design of Chiral Quaternary Ammonium Polymers for Asymmetric Catalysis Application
Md. Masud Parvez, Naoki Haraguchi, and Shinichi Itsuno
Org. Biomol. Chem.      2012年
Design of Main-chain Polymers of Chiral Imidazolidinone for Asymmetric Organocatalysis Application
Naoki Haraguchi, Hitomi Kiyono, Yu Takemura, and Shinichi Itsuno
Chem. Commun.      2012年
Proline Recognition through CH---Pi Interaction within Crystal Structures of DL-ProlineCalix[4]pyrogallolarene Molecular Complexes
Ikuhide Fujisawa, Noriko Harima, Kenji Takagi, Shuichi Hiraoka, Mitsuhiko Shionoya, Kazutaka Murayama, Shinichi Itsuno, Ryo Kato, and Katsuyuki Aoki
Bull. Chem. Soc. Jpn      2012年
Environmentally Benign Polymeric Organocatalyst: Synthesis of ChiralQuaternary Ammonium Salt Polymers and Their Use in Asymmetric Catalysis
Shinichi Itsuno and Naoki Haraguchi
3rd IUPAC Conference on Green Chemistry Proceeding      2011年
Shinichi Itsuno, Md Masud Parvez, Naoki Haraguchi
Polymer Chemistry   2 1942-1949   2011年9月
Incorporation of a chiral quaternary ammonium salt into a polymer allows for the preparation of a polymeric chiral organocatalyst that can be utilized in various asymmetric transformations in organic synthesis. Chiral quaternary ammonium salts are...
Supported Organocatalysts
Shinichi Itsuno, Naoki Haraguchi
Sci. Synth.      2011年
Polymeric chiral organocatalysts
Shinichi Itsuno, Masud Parbez, Naoki Haraguchi
Polym. Chem.      2011年
Naoki Haraguchi, Akihiro Nishiyama, Shinichi Itsuno
Journal of Polymer Science, Part A: Polymer Chemistry   48 3340-3349   2010年8月
Monodisperse, crosslinked poly(divinylbenzene) and poly(methacrylic acid-co-ethylene glycol dimethacrylate) microspheres with (1R,2R)-N 1-toluenesulfonyl-1,2-diphenylethylene-1,2-diamine ((R,R)-TsDPEN) moiety were successfully prepared by precipit...

Misc

 
Shinichi Itsuno
Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis      2011年6月
Shinichi Itsuno
Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis      2011年6月
This book reviews chiral polymer synthesis and its application to asymmetric catalysis. It features the design and use of polymer-immobilized catalysts and methods for their design and synthesis. Chapters cover peptide-catalyzed and enantioselecti...
Shinichi Itsuno
Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis   1-15   2011年6月
Naoki Haraguchi, Shinichi Itsuno
Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis   17-61   2011年6月
Naoki Haraguchi, Keiichi Tsuru, Yukihiro Arakawa, Shinichi Itsuno
Organic and Biomolecular Chemistry   7 69-75   2009年1月
The asymmetric transfer hydrogenation of imines was performed with the use of a polymer-immobilized chiral catalyst. The chiral catalyst, prepared from crosslinked polystyrene-immobilized chiral 1,2-diamine monosulfonamide, was effective in the as...

講演・口頭発表等

 
Synthesis of chiral polymers and their applications to asymmetric catalysis [招待有り]
伊津野 真一
Mukarram Hussain Khundkar (MHK) Memorial Lecture   2017年4月27日   
SmaSys 2016
Synthesis of chiral polymer catalysts and their application to asymmetric reactions
2016   
高分子コロキウム
Synthesis of chiral polymer catalysts and their application to asymmetric reactions
2016   
高分子討論会
高度な不斉触媒活性を有するキラル高分子の合成と不斉反応への応用
2016   
NCKU Chemistry Seminar
Design of Chiral Polymer Organocatalysts Derived from Cinchona Alkaloid and Amino Acid
2016   
ISOC 2015
Synthesis of Chiral Polymers of Cinchona Derived Organocatalyst and their Application to Asymmetric Catalysis
2015   
2014 International Symposium on Polymer Materials at Qiqihar
Synthesis of Chiral Transition Metal Complex Immobilized to Amphiphilic Polymers and Their Application to Asymmetric Catalysis
2014   
2014 International Symposium on Polymer Materials at Harbin
Chiral Polymers Containing Quaternary Ammonium Salt of Cinchona Alkaloid for Asymmetric Catalysis Application
2014   
旭川工業高等専門学校平成25年度特別講演
光学活性高分子の合成と不斉触媒への応用
2013   
科研費補助金新学術領域研究「元素ブロック高分子材料の創出」
不斉触媒機能を有するキラル元素ブロックの高分子化
2013   
Macromolecular Chemistry Seminar
Molecular design of optically active monomers and polymers for asymmetric catalysis application
2012   
Seminar in Department of Organic and Industrial Chemistry
Molecular design of optically active polymers for asymmetric catalysis application
2012   
Academia Sinica Chemistry Seminar
Molecular design of optically active polymers for asymmetric catalysis application
2011   
NHTU Organic Chemistry Seminar
Molecular design of optically active polymers for asymmetric catalysis application
2011   
NCTU chemistry department seminar
Molecular design of optically active polymers for asymmetric catalysis application
2011   
The 3rd Taiwan-Japan Bilateral Polymer Symposium 2011 (TJBPS’ 11)
Molecular design of main-chain chiral polymers for asymmetric catalysis application
2011   
??"
Design of Polymeric Chiral Catalysts and Their Use in Asymmetric Synthesis
2011   
Polymer Chemistry Seminar
Molecular Design of Chiral Polymers for Asymmetric Catalysis Application
2011   
Organic Chemistry Seminar
Molecular Design of Chiral Polymers for Asymmetric Catalysis Application
2011   
Seminar at Universite' Claude-Bernard Lyon1
Molecular design of chiral polymers for asymmetric catalysis application
2011   
Manchester University Chemistry Department Seminar
Molecular design of chiral polymers for asymmetric catalysis application
2010   
Grasgow Seminar
Immobilization Methods of Chiral Catalyst to Polymer and Asymmetric Reaction using Polymeric Catalyst
2010   
McMaster University Chemistry Department Seminar
Immobilization Methods of Chiral Catalyst to Polymer and Asymmetric Reaction using Polymeric Catalyst
2009   
Bangladesh Chemical Congress
Polymer-immobilized chiral catalyst in aqueous media: Enviromentally benign synthetic method of optically active compounds
2009   
Organisch-chemisches Kolloquium at Basel University
Polymer-Immobilized Chiral Catalyst for Asymmetric Reactions
2008   
"International Symposium on Advanced
Polymer-immobilized Chiral Catalyst for Asymmetric Reactions
2007
Designed Architechtures"
10   
2-Diamine Derivatives
"Polymer-supported Chiral 1
in Melts
in Inhomogeneous Systems
and Interfaces?Dresden   
Japan"
in Asia-Pacific Rim?Niigata
一般講演   
Korea"
Polymerization and Related Subjects?Gwangju
一般講演   
USA"
Polymer-Supported Catalyst in Water ?Orlando
一般講演   
2-Diamine Derivatives and their Application to
1
第6回高分子命名法シンポジウム
高分子命名法  最近の話題からー不斉重合の定義を中心に
2005   
Turkey"
Engineering APME 2005?Istanbul
一般講演   
技術交流会
不斉合成とコンビナトリアルケミストリー
2002   
13 Conference on Combinatorial Chemistry, Japan
キラル高分子の合成と不斉反応への応用
2001   
2001
Functional Polymers & Dendrimers"
4   
分子研研究会「21世紀の不斉分子科学」
不斉C−C結合形成反応を利用する光学活性高分子の不斉合成
2001   
Seminar on Asymmetric Synthesis
Asymmetric C-C Bond Forming Reactions"
2001   
INTERGRUPPEN SEMINAR at ETH
Asymmetric Reactions using Polymer-Support
2000   
シンポジウム「キラル高分子」、高分子学会北海道支部
キラルルイス酸触媒を用いる不斉重付加反応
2000   
IUPAC 9 International Conference on Polymer Based Technology
Polymer Assisted Asymmetric Reactions
2000   
"9 International Symposium on Fine Chemistry and
Polymer Assisted Asymmetric Synthesis
China"
Functional Polymers (FCFP-IX)?Haikou
一般講演   
National Research Council ICPET Seminar
Reagents and Catalysts"
1998   
"4 International Conference on Chemistry and Its
Asymmetric Synthesis using Polymer-Supported Catalysts
1997
Role in Development"
4