2015年3月
Reduced Grain Boundary Resistance by Surface Modification
JOURNAL OF PHYSICAL CHEMISTRY C
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- ,
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- 巻
- 119
- 号
- 10
- 開始ページ
- 5412
- 終了ページ
- 5419
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jp510077z
- 出版者・発行元
- AMER CHEMICAL SOC
Interfacial resistance is one of the severe problems in composite electrodes of all solid state batteries (ASSBS), especially oxide type ASSBs. Conflicts between poor sintetability and possible unfavorable reaction with active materials limit applicable materials and processes hi this report, a novel approach is proposed to decrease grain boundary resistance among nonsintered solid electrolyte particles. The concept is successfully demonstrated, and the nonsintered grain boundary resistance of a highly conducting solid electrolyte (Li1.3Al0.3Ti1.7(PO4)(3)) was suppressed by being coated with poorly conducting solid electrolyte (Li2SiO3). Increased total conductivity and variation of apparent activation energy are well explained from the viewpoint of defect cliernistry.
- リンク情報
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- DOI
- https://doi.org/10.1021/jp510077z
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000351189100018&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84924588025&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=84924588025&origin=inward
- ID情報
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- DOI : 10.1021/jp510077z
- ISSN : 1932-7447
- eISSN : 1932-7455
- SCOPUS ID : 84924588025
- Web of Science ID : WOS:000351189100018