論文

査読有り
2010年1月

Acoustic phonons and a central mode in the protonic conductor K3H(SeO4)(2)

PHYSICAL REVIEW B
  • Fumihito Shikanai
  • ,
  • Shinya Tsukada
  • ,
  • Jun Kano
  • ,
  • Seiji Kojima

81
1
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1103/PhysRevB.81.012301
出版者・発行元
AMER PHYSICAL SOC

The dynamical properties of protonic conductor K3H(SeO4)(2) were examined by Brillouin scattering. Both longitudinal-acoustic modes (c(33) and c(11)) and a transversal mode (c(44)) monotonously depend on temperature, and no soft mode was observed. A central mode with a width about 6 GHz was observed above phase-transition temperature, T-C. The central mode has a symmetry E-g corresponding to the rotational mode of SeO4 tetrahedra. The E-g mode is compatible with a zone-boundary soft mode, L-3, which accounts for the symmetrical change from R (3) over barm m to C2/c. The intensity of the central mode declines in the vicinity of T-C. This shows that chaotic rotational motion changes into a zone-boundary soft mode with decreasing temperature.

リンク情報
DOI
https://doi.org/10.1103/PhysRevB.81.012301
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000274001800005&DestApp=WOS_CPL
ID情報
  • DOI : 10.1103/PhysRevB.81.012301
  • ISSN : 2469-9950
  • eISSN : 2469-9969
  • Web of Science ID : WOS:000274001800005

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