論文

査読有り
2015年5月

NO Decomposition Activated by Preadsorption of O-2 onto Copper Cluster Anions

JOURNAL OF PHYSICAL CHEMISTRY C
  • Shinichi Hirabayashi
  • ,
  • Masahiko Ichihashi

119
20
開始ページ
10850
終了ページ
10855
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/jp510190e
出版者・発行元
AMER CHEMICAL SOC

Reactions of anionic copper cluster dioxides, CunO2- (n = 8, 10, and 12), with NO were studied in the gas phase by using a guided ion beam tandem mass spectrometer. A product ion, Cun-2O4-, is observed under multiple collision conditions together with the single,collision reaction products, Cu5O2NO- and Cun-1O2NO-: The NO-pressure dependence studies show that Cun-2O4- is formed via adsorption of two NO molecules followed by releasing an N-2 molecule, which is clear eViderite for NO decomposition. Density functional them calculations were also performed for the reaction of Cu8O2- with two NO Molecules and confirm the production of Cu6O4- under the experimental conditions used.

Web of Science ® 被引用回数 : 8

リンク情報
DOI
https://doi.org/10.1021/jp510190e
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000355158400008&DestApp=WOS_CPL

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