- AMER CHEMICAL SOC
Reactions of anionic copper cluster dioxides, CunO2- (n = 8, 10, and 12), with NO were studied in the gas phase by using a guided ion beam tandem mass spectrometer. A product ion, Cun-2O4-, is observed under multiple collision conditions together with the single,collision reaction products, Cu5O2NO- and Cun-1O2NO-: The NO-pressure dependence studies show that Cun-2O4- is formed via adsorption of two NO molecules followed by releasing an N-2 molecule, which is clear eViderite for NO decomposition. Density functional them calculations were also performed for the reaction of Cu8O2- with two NO Molecules and confirm the production of Cu6O4- under the experimental conditions used.
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