論文

査読有り
2012年4月

Reactions of copper cluster cations with nitrous oxide: Oxidation and sequential N2O adsorption

CHEMICAL PHYSICS LETTERS
  • Shinichi Hirabayashi
  • ,
  • Masahiko Ichihashi
  • ,
  • Tamotsu Kondow

533
開始ページ
15
終了ページ
19
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.cplett.2012.03.019
出版者・発行元
ELSEVIER SCIENCE BV

Reactions of size-selected copper cluster cations, Cu-n(+) (n = 3-7) and CunOm+ (n = 3-5; m = 1 and 2), with nitrous oxide molecules, N2O, have been investigated by use of a tandem mass spectrometer. N2O molecules adsorb sequentially on the odd-sized Cu-n+ to produce Cu-n(+) (N2O)(l), while the even-sized clusters give the reaction products, such as Cun-1O+(N2O)(l), involving both the oxidation and the N2O adsorption. Preadsorption of oxygen atoms promotes the sequential N2O-adsorption significantly, and in particular, Cu3O+(N2O)(3), Cu4O2+(N2O)(3), and Cu5O2+(N2O)(4) are produced dominantly from Cu3O+, Cu4O2+, and Cu5O2+, which shows the saturation of the adsorption with N2O. (C) 2012 Elsevier B. V. All rights reserved.

Web of Science ® 被引用回数 : 7

リンク情報
DOI
https://doi.org/10.1016/j.cplett.2012.03.019
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000302748400004&DestApp=WOS_CPL

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