論文

査読有り
2010年4月

Vibrational and electronic spectra of Co-n(+)(CH3OH)(3) (n=1-3) measured by infrared photodissociation spectroscopy

CHEMICAL PHYSICS LETTERS
  • Shinichi Hirabayashi
  • ,
  • Masahiko Ichihashi
  • ,
  • Yoshiyuki Kawazoe
  • ,
  • Tamotsu Kondow

490
1-3
開始ページ
19
終了ページ
23
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.cplett.2010.03.021
出版者・発行元
ELSEVIER SCIENCE BV

Photodissociation spectra of Co-n(+)(CH3OH)(3) (n = 1-3) were measured in the region of 2800-6800 cm(-1). A broad near-infrared (-IR) absorption was observed in the spectra of n = 2 and 3, in addition to the vibrational absorption in the mid-IR region. With the aid of a calculation based on time-dependent density functional theory (TD-DFT), the near-IR absorption is assigned to the electronic transitions between the levels located near the highest occupied and the lowest unoccupied levels of Co-n(+)(CH3OH)(3), in which one or two methanol molecules dissociate to CH3 and OH fragments and the fragments adsorb on the bridge sites of Co-n(+). (C) 2010 Elsevier B.V. All rights reserved.

Web of Science ® 被引用回数 : 4

リンク情報
DOI
https://doi.org/10.1016/j.cplett.2010.03.021
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000276258500005&DestApp=WOS_CPL

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