MISC

2014年5月

Measurement of two-dimensional distribution of surface supersaturation over a sodium chlorate crystal surface using multidirectional interferometry

CRYSTAL RESEARCH AND TECHNOLOGY
  • Kenta Murayama
  • ,
  • Katsuo Tsukamoto
  • ,
  • Atul Srivastava
  • ,
  • Hitoshi Miura
  • ,
  • Etsuro Yokoyama
  • ,
  • Yuki Kimura

49
5
開始ページ
315
終了ページ
322
記述言語
英語
掲載種別
DOI
10.1002/crat.201400010
出版者・発行元
WILEY-V C H VERLAG GMBH

The two-dimensional (2D) distributions of surface supersaturation of sodium chlorate crystals with and without solutal convection have been measured by means of a multidirectional interferometry (MDI) technique coupled with the principles of three-dimensional (3D) computer tomography. When solutal convection was present over a top face, the supersaturation at the center of the face was depleted by a factor of >0.9 with reference to the value at the edges of the crystal. When the convection was suppressed using an upside-down geometry, the depletion of supersaturation at the center of the face was much smaller, <0.4. Therefore, the supersaturation difference between the edges and the face center, which is responsible for the morphological stability due to volume diffusion for the solute, becomes less important compared to the effect of convection due to hydrodynamic reasons. This result should give us a key to solve why the crystal quality is sometimes better in convection-free microgravity conditions because of improved stability of a crystal face caused by more homogeneous distribution of supersaturation over the crystal surface.

リンク情報
DOI
https://doi.org/10.1002/crat.201400010
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000335519000006&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/crat.201400010
  • ISSN : 0232-1300
  • eISSN : 1521-4079
  • Web of Science ID : WOS:000335519000006

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