2010年11月
Thermal decomposition of alkaline-earth metal hydride and ammonia borane composites
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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- 巻
- 35
- 号
- 22
- 開始ページ
- 12405
- 終了ページ
- 12409
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.ijhydene.2010.08.018
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
We demonstrate a method to improve the promising hydrogen storage capabilities of ammonia borane by making composites with alkaline earth metal hydrides using ball milling technique The ball milling for the mixtures of alkaline earth metal hydride (MgH(2) or CaH(2)) and ammonia borane (AB) yields a destabilization compared with the ingredient of the mixture, showing the hydrogen capacity of 8 7 and 5 8 mass% at easily accessible dehydrogenation peak temperatures of 78 and 72 C respectively without the unwanted by product borazine Through detailed analyses on the dehydrogenation performance of the composite at various ratios in the hydride and AB we proposed a different chemical activation mechanism from that in the LiH/AB and NaH/AB systems reported in a previous literature (C) 2010 Professor T Nejat Veziroglu Published by Elsevier Ltd All rights reserved
- リンク情報
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- DOI
- https://doi.org/10.1016/j.ijhydene.2010.08.018
- CiNii Articles
- http://ci.nii.ac.jp/naid/120002753727
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000284298200030&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-77958152346&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0003-4600-3437
- ID情報
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- DOI : 10.1016/j.ijhydene.2010.08.018
- ISSN : 0360-3199
- CiNii Articles ID : 120002753727
- ORCIDのPut Code : 30160820
- SCOPUS ID : 77958152346
- Web of Science ID : WOS:000284298200030