An association of jadeite and omphacite has been newly found in an eclogite- facies metaquartz diorite collected from the Orco Valley area, southern part of the Eclogitic Micaschist Complex of the Sesia Zone, Western Alps, Italy. Both the jadeite and omphacite occur as idiomorphic to subidiomorphic grains in the matrix, and some of them are in contact with each other with a sharp grain boundary. Most of the jadeite shows faint and irregular zoning, with a chemical variation of X-jd ( Al-VI (jd) /( Na + Ca)) = 0.75- 0.90. Half of the omphacite grains is homogeneous, and the remainder shows various zoning patterns. Some omphacite grains exhibit prograde zoning with an increase in X-jd from 0.31 to 0.55 and a decrease in X-aeg (= Fe3+/( Na + Ca)) from 0.14 to 0.04 from the core to the rim. The rim composition of the zoned omphacite is similar to that of homogeneous omphacite ( X-jd = 0.40- 0.56). The average rim composition of the jadeite- omphacite pairs in direct contact shows an apparent miscibility gap between X-jd = 0.50 - 0.06, X-aeg = 0.09 - 0.03, and X-aug (= Ca/( Na + Ca)) = 0.41 - 0.05 in omphacite, and X-jd = 0.79 - 0.04, X-aeg = 0.08 - 0.03, and X-aug = 0.13 - 0.03 in jadeite. Application of Powell ( 1985) garnet- clinopyroxene geothermometer gives T = 470 - 30 - C at P = 12 kbar and application of Waters and Martin ( 1993) garnet- omphacite- phengite geobarometer gives P = 12.4 kbar at T = 440 - C and P = 12.0 kbar at T = 500 - C as peak metamorphic conditions. Composition data of the pyroxene P2/ n and C2/ c compositional fields obtained from both this study and the literature suggest that: ( 1) the shape of two miscibility gaps between jadeite and omphacite and between omphacite and augite in the jadeite- augite-aegirine phase diagram of Carpenter ( 1983) is more concordant with the natural data than that of Holland ( 1990), ( 2) the miscibility gap between omphacite and augite closes at T - 500 - C and P = 15 kbar, but the miscibility gap between jadeite and omphacite may still exist, and ( 3) the miscibility gap between jadeite and omphacite closes at T = 700- 850 - C and P = 15- 45 kbar.