2010年3月
Antiferromagnetic Interaction between A '-Site Mn Spins in A-Site-Ordered Perovskite YMn3Al4O12
INORGANIC CHEMISTRY
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- ,
- ,
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- 巻
- 49
- 号
- 5
- 開始ページ
- 2492
- 終了ページ
- 2495
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ic9024876
- 出版者・発行元
- AMER CHEMICAL SOC
The A-site-ordered perovskite YMn3Al4O12 was prepared by high-pressure synthesis. Structural analysis with synchrotron powder X-ray diffraction data and the Mn L-edges X-ray absorption spectrum revealed that the compound has a chemical composition Y3+Mn33+Al43+O122- with magnetic Mn3+ at the A' site and non-magnetic Al3+ at the B site. An antiferromagnetic interaction between the A'-site Mn3+ spins is induced by the nearest neighboring Mn-Mn direct exchange interaction and causes an antiferromagnetic transition at 34.3 K.
- リンク情報
- ID情報
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- DOI : 10.1021/ic9024876
- ISSN : 0020-1669
- eISSN : 1520-510X
- PubMed ID : 20108915
- Web of Science ID : WOS:000274626200057