論文

査読有り
2009年3月

Temperature-induced A-B intersite charge transfer in an A-site-ordered LaCu3Fe4O12 perovskite

NATURE
  • Y. W. Long
  • ,
  • N. Hayashi
  • ,
  • T. Saito
  • ,
  • M. Azuma
  • ,
  • S. Muranaka
  • ,
  • Y. Shimakawa

458
7234
開始ページ
60
終了ページ
U3
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1038/nature07816
出版者・発行元
NATURE PUBLISHING GROUP

Changes of valence states in transition-metal oxides often cause significant changes in their structural and physical properties(1,2). Chemical doping is the conventional way of modulating these valence states. In ABO(3) perovskite and/or perovskite-like oxides, chemical doping at the A site can introduce holes or electrons at the B site, giving rise to exotic physical properties like high-transition-temperature superconductivity and colossal magneto-resistance(3,4). When valence-variable transition metals at two different atomic sites are involved simultaneously, we expect to be able to induce charge transfer-and, hence, valence changes by using a small external stimulus rather than by introducing a doping element. Materials showing this type of charge transfer are very rare, however, and such externally induced valence changes have been observed only under extreme conditions like high pressure(5,6). Here we report unusual temperature-induced valence changes at the A and B sites in the A-site-ordered double perovskite LaCu3Fe4O12; the underlying intersite charge transfer is accompanied by considerable changes in the material's structural, magnetic and transport properties. When cooled, the compound shows a first-order, reversible transition at 393 K from LaCu32+Fe43.75+O12 with Fe3.75+ ions at the B site to LaCu33+Fe43+O12 with rare Cu3+ ions at the A site. Intersite charge transfer between the A-site Cu and B-site Fe ions leads to paramagnetism-to-antiferromagnetism and metal-to-insulator isostructural phase transitions. What is more interesting in relation to technological applications is that this above-room-temperature transition is associated with a large negative thermal expansion.

リンク情報
DOI
https://doi.org/10.1038/nature07816
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/19262669
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000263836000032&DestApp=WOS_CPL
ID情報
  • DOI : 10.1038/nature07816
  • ISSN : 0028-0836
  • PubMed ID : 19262669
  • Web of Science ID : WOS:000263836000032

エクスポート
BibTeX RIS