2013年8月
Magnetocaloric effect of field-induced ferromagnet BaFeO3
JOURNAL OF APPLIED PHYSICS
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- 巻
- 114
- 号
- 7
- 開始ページ
- 1
- 終了ページ
- 6
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1063/1.4818316
- 出版者・発行元
- AMER INST PHYSICS
We have investigated the magnetocaloric effect (MCE) of a perovskite oxide, BaFeO3, that shows ferromagnetism by the aid of a small external field of similar to 3 kOe (3.5 mu(B)/Fe, T-C = 111K). The magnetization is found to change almost reversibly in both field and temperature cycles. Hence, magnetic and thermal hysteretic losses are negligibly low during refrigeration, a property that is suitable for application. The reversible MCE is likely to arise from the absence of an orbital magnetic moment of Fe ions which are essentially in the Fe3+(L) under bar state ((L) under bar: ligand hole). The magnetic entropy change and refrigerant capacity near the T-C are similar to 5.8 J kg(-1) K-1 and similar to 172 J kg(-1), respectively, both of which are comparable to those of ferromagnetic perovskite manganites. As BaFeO3 contains no rare metals and is stable against corrosion, the material can be regarded as a candidate refrigerant material. (C) 2013 AIP Publishing LLC.
- リンク情報
- ID情報
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- DOI : 10.1063/1.4818316
- ISSN : 0021-8979
- ORCIDのPut Code : 34692287
- Web of Science ID : WOS:000323510900041
- ORCIDで取得されたその他外部ID : a:1:{i:0;a:1:{s:8:"other-id";s:19:"WOS:000323510900041";}}