2015年
Kinetic analysis for the isomerization of glucose, fructose, and mannose in subcritical aqueous ethanol
Bioscience, Biotechnology, and Biochemistry
- ,
- ,
- 巻
- 79
- 号
- 6
- 開始ページ
- 1005
- 終了ページ
- 1010
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1080/09168451.2014.1003129
- 出版者・発行元
- TAYLOR & FRANCIS LTD
Fructose, glucose, and mannose were treated with subcritical aqueous ethanol for ethanol concentrations ranging from 0 to 80% (v/v) at 180-200 degrees C. The aldose-ketose isomerization was more favorable than ketose-aldose isomerization and glucose-mannose epimerization. The isomerization of the monosaccharides was promoted by the addition of ethanol. In particular, mannose was isomerized most easily to fructose in subcritical aqueous ethanol. The apparent equilibrium constants for the isomerizations of mannose to fructose, K-eq,K-M -> F, and glucose to fructose, K-eq,K-G -> F, were independent of ethanol concentration and increased with increasing temperature. Moreover, the K-eq,K-M -> F value was much larger than the K-eq,K-G -> F value. The enthalpies for the isomerization of mannose to fructose, Delta H-M -> F, and glucose to fructose, Delta H-G -> F, were estimated to be 18 and 24kJ/mol, respectively, according to van't Hoff equation. Subcritical aqueous ethanol can be used to produce fructose from glucose and mannose efficiently.
- リンク情報
- ID情報
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- DOI : 10.1080/09168451.2014.1003129
- ISSN : 0916-8451
- eISSN : 1347-6947
- Web of Science ID : WOS:000356239400020