Papers

Peer-reviewed
Dec, 2015

Indium-Catalyzed [2+2] Cycloaddition of Allylsilanes to Internal Alkynones

ORGANIC LETTERS
  • Kazuhiro Okamoto
    • ,
  • Takuya Shimbayashi
    • ,
  • Eisuke Tamura
    • ,
  • Kouichi Ohe
Volume
17
Number
23
First page
5843
Last page
5845
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1021/acs.orglett.5b03065
Publisher
AMER CHEMICAL SOC
We have developed an indium-catalyzed [2 + 2] cydo-addition of allylsilanes to alkynones leading to selective cydobutenone formation. The resulting cydobutenones were readily converted to the oxidized products by Tamao-Fleming oxidation or the ring-opened products by an electrocyclic reaction.
Link information
DOI
https://doi.org/10.1021/acs.orglett.5b03065
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000366152000031&DestApp=WOS_CPL
ID information
  • DOI : 10.1021/acs.orglett.5b03065
  • ISSN : 1523-7060
  • eISSN : 1523-7052
  • Web of Science ID : WOS:000366152000031
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