2017年7月
Copper-Catalyzed Regio- and Stereoselective lodocyanation and Dicyanation of Alkynes with Cyanogen Iodide
ORGANIC LETTERS
- ,
- ,
- ,
- ,
- 巻
- 19
- 号
- 13
- 開始ページ
- 3422
- 終了ページ
- 3425
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.orglett.7b01378
- 出版者・発行元
- AMER CHEMICAL SOC
anti-Selective iodocyanation and dicyanation of various internal alkynes has been developed by means of a simple copper catalyst system. The selectivity of the products was switched by tuning the reaction conditions. Mechanistic studies have revealed all of the stepwise pathways including diiodide formation, selective monocyanation, and second cyanation processes.
Web of Science ® 被引用回数 : 16
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