論文

査読有り
2017年7月

Copper-Catalyzed Regio- and Stereoselective lodocyanation and Dicyanation of Alkynes with Cyanogen Iodide

ORGANIC LETTERS
  • Naoki Sakata
  • ,
  • Kohei Sasakura
  • ,
  • Gaku Matsushita
  • ,
  • Kazuhiro Okamoto
  • ,
  • Kouichi Ohe

19
13
開始ページ
3422
終了ページ
3425
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acs.orglett.7b01378
出版者・発行元
AMER CHEMICAL SOC

anti-Selective iodocyanation and dicyanation of various internal alkynes has been developed by means of a simple copper catalyst system. The selectivity of the products was switched by tuning the reaction conditions. Mechanistic studies have revealed all of the stepwise pathways including diiodide formation, selective monocyanation, and second cyanation processes.

Web of Science ® 被引用回数 : 16

リンク情報
DOI
https://doi.org/10.1021/acs.orglett.7b01378
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000405358300023&DestApp=WOS_CPL

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