論文

査読有り
2012年

Alkyne-coordinating tridentate ligands: structural properties and reactivity of their rhodium complexes

DALTON TRANSACTIONS
  • Kazuhiro Okamoto
  • ,
  • Yusuke Omoto
  • ,
  • Hayato Sano
  • ,
  • Kouichi Ohe

41
36
開始ページ
10926
終了ページ
10929
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c2dt31322g
出版者・発行元
ROYAL SOC CHEMISTRY

Complexes of novel alkyne-chelating tridentate ligands bound to a rhodium atom were isolated and characterised. The present alkyne-rhodium complex underwent dimerisation simply by heating to afford the unprecedented cyclobutadiene dirhodium complex. It is also found that the ligands at the trans positions influence the pi-coordination of alkynes.

Web of Science ® 被引用回数 : 22

リンク情報
DOI
https://doi.org/10.1039/c2dt31322g
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000308097900008&DestApp=WOS_CPL

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