2012
Alkyne-coordinating tridentate ligands: structural properties and reactivity of their rhodium complexes
DALTON TRANSACTIONS
- ,
- ,
- ,
- Volume
- 41
- Number
- 36
- First page
- 10926
- Last page
- 10929
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1039/c2dt31322g
- Publisher
- ROYAL SOC CHEMISTRY
Complexes of novel alkyne-chelating tridentate ligands bound to a rhodium atom were isolated and characterised. The present alkyne-rhodium complex underwent dimerisation simply by heating to afford the unprecedented cyclobutadiene dirhodium complex. It is also found that the ligands at the trans positions influence the pi-coordination of alkynes.
- Link information
- ID information
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- DOI : 10.1039/c2dt31322g
- ISSN : 1477-9226
- Web of Science ID : WOS:000308097900008