2020年5月13日
Probing dynamics of carbon dioxide in a metal-organic framework under high pressure by high-resolution solid-state NMR.
Physical chemistry chemical physics : PCCP
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- 巻
- 22
- 号
- 26
- 開始ページ
- 14465
- 終了ページ
- 14470
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1039/d0cp01216e
- 出版者・発行元
- Royal Society of Chemistry (RSC)
The application of high-resolution NMR analysis for CO2 adsorbed in a MOF under high pressure is reported for the first time. The results showed that CO2 adsorbed in MOF-74 had an unusually slow mobility (τ ∼ 10-8 s). CO2-CO2 interactions suppressed the mobility of CO2 under high pressure, which, in turn, would have contributed to the stability of CO2 at the adsorption sites.
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