2011年12月
Strain Effect on Structural Transition in SrRuO3 Epitaxial Thin Films
CRYSTAL GROWTH & DESIGN
- ,
- 巻
- 11
- 号
- 12
- 開始ページ
- 5483
- 終了ページ
- 5487
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/cg201070n
- 出版者・発行元
- AMER CHEMICAL SOC
We carried out detailed structural characterizations across the structural transition in SrRuO3 epitaxial thin films grown on SrTiO3 (001)(pc) substrate. The fabricated films undergo a structural transition from the low-temperature orthorhombic phase to the high-temperature pseudocubic phase at 280 degrees C. We find that, for films thinner than 20 nm, the transition becomes broader while thicker films display a sharp transition. Detailed X-ray diffraction measurements including reciprocal space mappings at various temperatures also reveal that the thinner films have a distorted orthorhombic unit cell resulting from the strain-induced additional rotation in the RuO6 octahedra, while, for the high-temperature pseudocubic phase, the film structure remains the same irrespective of film thickness. The results strongly suggest that the substrate-induced strain has a strong influence on the RuO6 rotation pattern in the epitaxial thin films
- リンク情報
- ID情報
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- DOI : 10.1021/cg201070n
- ISSN : 1528-7483
- ORCIDのPut Code : 30083102
- Web of Science ID : WOS:000297609100042
- ORCIDで取得されたその他外部ID : a:1:{i:0;a:1:{s:8:"other-id";s:19:"WOS:000297609100042";}}