論文

査読有り
2012年10月

Facile "Modular Assembly" for Fast Construction of a Highly Oriented Crystalline MOF Nanofilm

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Gang Xu
  • ,
  • Teppei Yamada
  • ,
  • Kazuya Otsubo
  • ,
  • Shun Sakaida
  • ,
  • Hiroshi Kitagawa

134
40
開始ページ
16524
終了ページ
16527
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ja307953m
出版者・発行元
AMER CHEMICAL SOC

The preparation of crystalline, ordered thin films of metal-organic frameworks (MOFs) will be a critical process for MOF-based nanodevices in the future. MOF thin films with perfect orientation and excellent crystallinity were formed with novel nanosheet-structured components, Cu-TCPP [TCPP = 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin], by a new "modular assembly" strategy. The modular assembly process involves two steps: a "modularization" step is used to synthesize highly crystalline "modules" with a nanosized structure that can be conveniently assembled into a thin film in the following "assembly" step. With this method, MOF thin films can easily be set up on different substrates at very high speed with controllable thickness. This new approach also enabled us to prepare highly oriented crystalline thin films of MOFs that cannot be prepared in thin-film form by traditional techniques.

リンク情報
DOI
https://doi.org/10.1021/ja307953m
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201202201428133520
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/23030459
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000309566400020&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/ja307953m
  • ISSN : 0002-7863
  • J-Global ID : 201202201428133520
  • PubMed ID : 23030459
  • Web of Science ID : WOS:000309566400020

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