2012年10月
Facile "Modular Assembly" for Fast Construction of a Highly Oriented Crystalline MOF Nanofilm
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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- 巻
- 134
- 号
- 40
- 開始ページ
- 16524
- 終了ページ
- 16527
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja307953m
- 出版者・発行元
- AMER CHEMICAL SOC
The preparation of crystalline, ordered thin films of metal-organic frameworks (MOFs) will be a critical process for MOF-based nanodevices in the future. MOF thin films with perfect orientation and excellent crystallinity were formed with novel nanosheet-structured components, Cu-TCPP [TCPP = 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin], by a new "modular assembly" strategy. The modular assembly process involves two steps: a "modularization" step is used to synthesize highly crystalline "modules" with a nanosized structure that can be conveniently assembled into a thin film in the following "assembly" step. With this method, MOF thin films can easily be set up on different substrates at very high speed with controllable thickness. This new approach also enabled us to prepare highly oriented crystalline thin films of MOFs that cannot be prepared in thin-film form by traditional techniques.
- リンク情報
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- DOI
- https://doi.org/10.1021/ja307953m
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201202201428133520
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/23030459
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000309566400020&DestApp=WOS_CPL
- ID情報
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- DOI : 10.1021/ja307953m
- ISSN : 0002-7863
- J-Global ID : 201202201428133520
- PubMed ID : 23030459
- Web of Science ID : WOS:000309566400020