2018年6月4日
Modular Cavities: Induced Fit of Polar and Apolar Guests into Halogen-Based Receptors
Inorganic Chemistry
- ,
- ,
- ,
- ,
- 巻
- 57
- 号
- 11
- 開始ページ
- 6222
- 終了ページ
- 6225
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/acs.inorgchem.8b01069
- 出版者・発行元
- American Chemical Society
Neutral triangular macrocyclic compounds, [PdX2(4,7-phen)]3·(DMF)3·Et2O (X = Cl, Br
4,7-phen = 4,7-phenanthroline
DMF = N,N′-dimethylformamide
Et2O = diethyl ether), were synthesized, and their molecular structures were characterized. Solution-state 1H NMR results suggested the formation of metal-ligand bonds, and single-crystal X-ray crystallography revealed clear triangular structures. A detailed examination of the structures indicated the formation of two kinds of cavities in the solid state, where a triangular unit works as a halogen-based receptor for polar and apolar solvents through weak hydrogen-bonding and dipole-dipole interaction.
4,7-phen = 4,7-phenanthroline
DMF = N,N′-dimethylformamide
Et2O = diethyl ether), were synthesized, and their molecular structures were characterized. Solution-state 1H NMR results suggested the formation of metal-ligand bonds, and single-crystal X-ray crystallography revealed clear triangular structures. A detailed examination of the structures indicated the formation of two kinds of cavities in the solid state, where a triangular unit works as a halogen-based receptor for polar and apolar solvents through weak hydrogen-bonding and dipole-dipole interaction.
- ID情報
-
- DOI : 10.1021/acs.inorgchem.8b01069
- ISSN : 1520-510X
- ISSN : 0020-1669
- ORCIDのPut Code : 45084640
- SCOPUS ID : 85048306072