2019年9月
A Novel Platinum(III)-Platinum(III) Neutral Dimer Complex, Pt-2(cdtb)(4)I-2 (cdtb: 4-Cyanodithiobenzoate)
CHEMISTRY LETTERS
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- 巻
- 48
- 号
- 9
- 開始ページ
- 1035
- 終了ページ
- 1037
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1246/cl.190355
- 出版者・発行元
- 公益社団法人 日本化学会
<p>A novel Pt(III)–Pt(III) neutral dimer complex, Pt2(cdtb)4I2 (cdtb: 4-cyanodithiobenzoate) was successfully synthesized by the solvothermal method. Single-crystal X-ray structure analysis clearly revealed its molecular structure, where the Pt–Pt distance was 2.582(1) Å. Characteristic vibration modes and absorption bands derived from the Pt dimer structure were clearly observed in Raman and electronic absorption spectra, respectively, and the results were supported by density functional theory calculations.</p>
- リンク情報
- ID情報
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- DOI : 10.1246/cl.190355
- ISSN : 0366-7022
- CiNii Articles ID : 130007703014
- Web of Science ID : WOS:000478698100005