2015年
Asymmetric Suzuki-Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos
CHEMICAL COMMUNICATIONS
- ,
- ,
- ,
- 巻
- 51
- 号
- 33
- 開始ページ
- 7211
- 終了ページ
- 7214
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c5cc01074h
- 出版者・発行元
- ROYAL SOC CHEMISTRY
A single-handed helical polymer ligand PQXphos afforded axially chiral biaryl esters with high enantioselectivities in asymmetric Suzuki-Miyaura cross-coupling. The use of naphthyl bromide bearing a 2,4-dimethyl-3-pentyl ester resulted in both high yields and high enantioselectivities. Either enantiomer could be synthesized selectively by using a single PQXphos through a solvent-dependent switch of the helical chirality.
- リンク情報
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- DOI
- https://doi.org/10.1039/c5cc01074h
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/25812517
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000352863600031&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84927750106&origin=inward
- ID情報
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- DOI : 10.1039/c5cc01074h
- ISSN : 1359-7345
- eISSN : 1364-548X
- PubMed ID : 25812517
- SCOPUS ID : 84927750106
- Web of Science ID : WOS:000352863600031