2011年
O2- -to-F- substitution on the quasi-two-dimensional quantum antiferromagnet (CuCl)LaNb2O7
INTERNATIONAL CONFERENCE ON FRUSTRATION IN CONDENSED MATTER (ICFCM)
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- 巻
- 320
- 号
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1088/1742-6596/320/1/012036
- 出版者・発行元
- IOP PUBLISHING LTD
We present the preparation of the electron-doped quasi-two dimensional quantum antiferromagnet (CuCl)LaNb2O7 by two step-wise topochemical reactions. The first step involves a reductive fluorination of the insulating layered perovskite RbLaNb2O7 using polytetrafluoroethylene that allows electric conduction in the perovskite blocks. The product RbLaNb2O6F was then ion-exchanged with copper dichloride to yield (CuCl) LaNb2O6F. The synchrotron x-ray diffraction study indicates that the structure of the final compound is different from that of the pure (CuCl)LaNb2O7.
- リンク情報
- ID情報
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- DOI : 10.1088/1742-6596/320/1/012036
- ISSN : 1742-6588
- Web of Science ID : WOS:000299350600036