MISC

2009年11月

Racemic (RS <inf>C</inf>,SR <inf>S</inf>)-(2-{[1-allyl-oxy-carbonyl-3- (methyl-sulfanyl)prop-yl]iminometh-yl}phenyl-κ3 S,N,C 1)chlorido-platinum(II)

Acta Crystallographica Section E: Structure Reports Online
  • Katsuhiro Isozaki
  • ,
  • Akira Sato
  • ,
  • Kazushi Miki
  • ,
  • Kazushi Miki

65
開始ページ
M1401
終了ページ
U1458
記述言語
英語
掲載種別
DOI
10.1107/S160053680904238X

The title compound, [Pt(C15H18NO2S)Cl], was obtained by the cyclo-metallation reaction of cis-bis-(benzonitrile) dichlorido-platinum(II) with N-benzyl-idene-l-methio-nine allyl ester in refluxing toluene. The PtII atom has a square-planar geometry and is tetra-coordinated by the Cl atom and the C, N and S atoms from the benzyl-idene methio-nine ester ligand. In the crystal structure, the S atoms show opposite chiral configurations with respect to the-carbon of the methio-nine, reducing steric repulsion between the methyl and allyl ester groups.

リンク情報
DOI
https://doi.org/10.1107/S160053680904238X
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000271906600112&DestApp=WOS_CPL
URL
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=70449413184&origin=inward
ID情報
  • DOI : 10.1107/S160053680904238X
  • ISSN : 1600-5368
  • SCOPUS ID : 70449413184
  • Web of Science ID : WOS:000271906600112

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