2009年11月
Racemic (RS <inf>C</inf>,SR <inf>S</inf>)-(2-{[1-allyl-oxy-carbonyl-3- (methyl-sulfanyl)prop-yl]iminometh-yl}phenyl-κ3 S,N,C 1)chlorido-platinum(II)
Acta Crystallographica Section E: Structure Reports Online
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- 巻
- 65
- 号
- 開始ページ
- M1401
- 終了ページ
- U1458
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1107/S160053680904238X
The title compound, [Pt(C15H18NO2S)Cl], was obtained by the cyclo-metallation reaction of cis-bis-(benzonitrile) dichlorido-platinum(II) with N-benzyl-idene-l-methio-nine allyl ester in refluxing toluene. The PtII atom has a square-planar geometry and is tetra-coordinated by the Cl atom and the C, N and S atoms from the benzyl-idene methio-nine ester ligand. In the crystal structure, the S atoms show opposite chiral configurations with respect to the-carbon of the methio-nine, reducing steric repulsion between the methyl and allyl ester groups.
- リンク情報
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- DOI
- https://doi.org/10.1107/S160053680904238X
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000271906600112&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=70449413184&origin=inward
- ID情報
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- DOI : 10.1107/S160053680904238X
- ISSN : 1600-5368
- SCOPUS ID : 70449413184
- Web of Science ID : WOS:000271906600112