論文

査読有り
2017年9月

Strategic Construction of Directly Linked Porphyrin-BODIPY Hybrids

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  • Lei Xu
  • Bin Wen
  • Gakhyun Kim
  • Taeyeon Kim
  • Fei Cheng
  • Mingbo Zhou
  • Ling Xu
  • Takayuki Tanaka
  • Bangshao Yin
  • Atsuhiro Osuka
  • Dongho Kim
  • Jianxin Song
  • 全て表示

56
40
開始ページ
12322
終了ページ
12326
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/anie.201707237
出版者・発行元
WILEY-V C H VERLAG GMBH

A powerful and concise synthesis of directly linked porphyrin-BODIPY hybrids has been demonstrated, which consists of condensation of directly linked meso-pyrroyl Ni-II-porphyrin with arylaldehyde, oxidation with p-chloranil, and complexation with BF3Et2O. Synthesized hybrids include porphyrin dimer 6Ni, trimers 8Ni, 9Ni, tetramer 12Ni, pentamer 16Ni, hexamer 13Ni, and nonamers 17Ni and 18Ni. The structures of 6Ni, 9Ni and 12Ni were unambiguously confirmed by X-ray diffraction analysis. Some Ni-II porphyrins were effectively converted to the corresponding Zn-II porphryins. In these hybrids, the pigments are three-dimensionally arranged with a face-to-face dimeric porphyrin unit in a well-defined manner, featuring their potential as light-harvesting antenna and functional hosts.

リンク情報
DOI
https://doi.org/10.1002/anie.201707237
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000411267800052&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/anie.201707237
  • ISSN : 1433-7851
  • eISSN : 1521-3773
  • Web of Science ID : WOS:000411267800052

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