2014年
Strongest pi-metal orbital coupling in a porphyrin/gold cluster system
CHEMICAL SCIENCE
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- 巻
- 5
- 号
- 5
- 開始ページ
- 2007
- 終了ページ
- 2010
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1039/c3sc53460j
- 出版者・発行元
- ROYAL SOC CHEMISTRY
Face-on and close configuration of a p-conjugated molecule on an Au cluster generates a strong p-metal coupling between the p and metal orbitals. We successfully synthesized porphyrin-coordinated Au clusters in face-on configuration at the closest distance. The interaction between the Au cluster and porphyrin was investigated by UV-vis-NIR and transient absorption measurement.
- リンク情報
- ID情報
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- DOI : 10.1039/c3sc53460j
- ISSN : 2041-6520
- eISSN : 2041-6539
- Web of Science ID : WOS:000334492700042