2020年9月25日
Multicomponent 3d Transition-Metal Nanoparticles as Catalysts Free of Pd, Pt, or Rh for Automotive Three-Way Catalytic Converters
ACS Applied Nano Materials
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- 巻
- 3
- 号
- 9
- 開始ページ
- 9097
- 終了ページ
- 9107
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acsanm.0c01769
- 出版者・発行元
- American Chemical Society ({ACS})
Copyright © 2020 American Chemical Society. Multicomponent 3d transition-metal nanoparticles supported on Al2O3 were prepared using a complex polymerization process and a post H2-reduction treatment at 900 °C. Catalysts in a binary system were divided into two groups: single-phase alloys (NiCu and FeNi) and immiscible two-phase mixtures (FeCu and CoCu), whereas ternary (FeNiCu and CoNiCu) and quaternary (FeCoNiCu) catalysts produced single-alloy nanoparticles. The ternary and quaternary alloy catalysts achieved high NO reduction in a stoichiometric NO-CO-C3H6-O2 reaction under wet conditions (5% H2O), which simulates automotive three-way catalysis (TWC). In contrast, the activity of unary and binary systems of these metal elements significantly deteriorated in the presence of H2O. Cu-based metal catalysts are efficient for NO reduction, but they are easily deactivated by oxidation to less active oxides in the presence of O2 and/or H2O. The superiority of the multinary alloy catalysts is a result of the higher stability and regenerability of the metallic Cu species. Therefore, increasing the number of metal elements in alloy nanoparticles can provide a phase stabilization against oxidation under TWC conditions.
- リンク情報
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- DOI
- https://doi.org/10.1021/acsanm.0c01769
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000575846000057&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85094652800&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85094652800&origin=inward
- ID情報
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- DOI : 10.1021/acsanm.0c01769
- ISSN : 2574-0970
- eISSN : 2574-0970
- ORCIDのPut Code : 79121446
- SCOPUS ID : 85094652800
- Web of Science ID : WOS:000575846000057