論文

査読有り
2015年9月

Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Munehiro Inukai
  • ,
  • Tomohiro Fukushima
  • ,
  • Yuh Hijikata
  • ,
  • Naoki Ogiwara
  • ,
  • Satoshi Horike
  • ,
  • Susumu Kitagawa

137
38
開始ページ
12183
終了ページ
12186
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/jacs.5b05413
出版者・発行元
AMER CHEMICAL SOC

Rational design to control the dynamics of molecular rotors in crystalline solids is of interest because it offers advanced materials with precisely tuned functionality. Herein, we describe the control of the rotational frequency of rotors in flexible porous coordination polymers (PCPs) using a solid-solution approach. Solid-solutions of the flexible PCPs [{Zn(5-nitroisophthalate)(x)(5-methoxyisophthalate)(1-x)(deuterated 4,4'-bipyridyl)}(DMF-MeOH)](n) allow continuous modulation of cell volume by changing the solid-solution ratio x. Variation of the isostructures provides continuous changes in the local environment around the molecular rotors (pyridyl rings of the 4,4'-bipyridyl group), leading to the control of the rotational frequency without the need to vary the temperature.

Web of Science ® 被引用回数 : 44

リンク情報
DOI
https://doi.org/10.1021/jacs.5b05413
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000362243300004&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-84942881728&partnerID=MN8TOARS
URL
http://orcid.org/0000-0003-4830-6888

エクスポート
BibTeX RIS