論文

査読有り
2015年2月

Study on a 2D layer coordination framework showing order-to-disorder phase transition by ionothermal synthesis

POLYMER JOURNAL
  • Wenqian Chen
  • ,
  • Satoshi Horike
  • ,
  • Munehiro Inukai
  • ,
  • Susumu Kitagawa

47
2
開始ページ
141
終了ページ
145
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1038/pj.2014.100
出版者・発行元
NATURE PUBLISHING GROUP

In this study, a two-dimensional (2D) layer-type coordination framework showing solid-to-solid phase transition was ionothermally synthesized. [Zn-2(SO4)(3)(bpy)](THMA)(2) contains an anionic 2D grid layer-type coordination framework and an ordered bulky ammonium cation, THMA(+), with multiple hydrogen bonds. The compound shows reversible order-to-disorder transformation, a result of the cations, which were characterized using X-ray diffraction, differential scanning calorimetry and solid state nuclear magnetic resonance. This study suggests the potential use of coordination frameworks, prepared by ionothermal synthesis, in the design of new type of materials that show solid-to-solid phase transition and high thermal stability for dielectric, ferroelectric and electro-optic functions.

Web of Science ® 被引用回数 : 2

リンク情報
DOI
https://doi.org/10.1038/pj.2014.100
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000349473600011&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-84922325926&partnerID=MN8TOARS
URL
http://orcid.org/0000-0003-4830-6888

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