論文

査読有り
2014年

Template-directed proton conduction pathways in a coordination framework

JOURNAL OF MATERIALS CHEMISTRY A
  • Munehiro Inukai
  • ,
  • Satoshi Horike
  • ,
  • Wenqian Chen
  • ,
  • Daiki Umeyama
  • ,
  • Tomoya Itakura
  • ,
  • Susumu Kitagawa

2
27
開始ページ
10404
終了ページ
10409
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c4ta01261e
出版者・発行元
ROYAL SOC CHEMISTRY

We present a strategy for creating coordination frameworks exhibiting proton conduction with thermal stability. The coordination framework, where template cations link 1-D chains via hydrogen bonds, has dynamic hydrogen bond networks where protons move without water support. Solid-state NMR and X-ray studies visualized the proton hopping mechanism, and revealed that the templates provide the bridging of the 1-D chains to attain proton conduction. The templates also enable the proton conductive networks to be maintained at 190 degrees C through multiple interactions between the templates and the 1-D chains.

Web of Science ® 被引用回数 : 28

リンク情報
DOI
https://doi.org/10.1039/c4ta01261e
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000338124500012&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-84902802354&partnerID=MN8TOARS
URL
http://orcid.org/0000-0003-4830-6888

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