2014
Template-directed proton conduction pathways in a coordination framework
JOURNAL OF MATERIALS CHEMISTRY A
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- Volume
- 2
- Number
- 27
- First page
- 10404
- Last page
- 10409
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1039/c4ta01261e
- Publisher
- ROYAL SOC CHEMISTRY
We present a strategy for creating coordination frameworks exhibiting proton conduction with thermal stability. The coordination framework, where template cations link 1-D chains via hydrogen bonds, has dynamic hydrogen bond networks where protons move without water support. Solid-state NMR and X-ray studies visualized the proton hopping mechanism, and revealed that the templates provide the bridging of the 1-D chains to attain proton conduction. The templates also enable the proton conductive networks to be maintained at 190 degrees C through multiple interactions between the templates and the 1-D chains.
- Link information
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- DOI
- https://doi.org/10.1039/c4ta01261e
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000338124500012&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-84902802354&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0003-4830-6888
- ID information
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- DOI : 10.1039/c4ta01261e
- ISSN : 2050-7488
- eISSN : 2050-7496
- ORCID - Put Code : 44202482
- SCOPUS ID : 84902802354
- Web of Science ID : WOS:000338124500012