論文

査読有り 国際誌
2020年5月13日

Probing dynamics of carbon dioxide in a metal-organic framework under high pressure by high-resolution solid-state NMR.

Physical chemistry chemical physics : PCCP
  • Munehiro Inukai
  • ,
  • Takuya Kurihara
  • ,
  • Yasuto Noda
  • ,
  • Weiming Jiang
  • ,
  • Kiyonori Takegoshi
  • ,
  • Naoki Ogiwara
  • ,
  • Hiroshi Kitagawa
  • ,
  • Koichi Nakamura

記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/d0cp01216e

The application of high-resolution NMR analysis for CO2 adsorbed in a MOF under high pressure is reported for the first time. The results showed that CO2 adsorbed in MOF-74 had an unusually slow mobility (τ ∼ 10-8 s). CO2-CO2 interactions suppressed the mobility of CO2 under high pressure, which, in turn, would have contributed to the stability of CO2 at the adsorption sites.

リンク情報
DOI
https://doi.org/10.1039/d0cp01216e
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/32400799

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