2015年4月
Total Synthesis of Ellagitannins through Regioselective Sequential Functionalization of Unprotected Glucose
Angewandte Chemie International Edition
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- 巻
- 54
- 号
- 21
- 開始ページ
- 6177
- 終了ページ
- 6180
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/anie.201500700
- 出版者・発行元
- wiley
Article first published online: 9 APR 2015Short total syntheses of natural glycosides (ellagitannins) were performed through sequential and regioselective functionalization of the hydroxy groups of unprotected glucose. The key reactions are β-selective glycosidation of a gallic acid derivative by using unprotected glucose as a glycosyl donor and catalyst-controlled regioselective introduction of a galloyl group into the inherently less reactive hydroxy group of the glucoside.
- リンク情報
- ID情報
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- DOI : 10.1002/anie.201500700
- ISSN : 1433-7851
- CiNii Articles ID : 120005676700
- CiNii Books ID : AA0052535X