2006年4月
A novel octanuclear manganese cluster with [MnII4(μ4-O)] core
Chemistry Letters
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- 巻
- 35
- 号
- 4
- 開始ページ
- 440
- 終了ページ
- 441
- 記述言語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1246/cl.2006.440
The reaction of MnCl2·4H2O with 2-aminoethanethiol (= Haet) under anaerobic conditions afforded yellow plate crystals of octanuclear manganese complex [Mn4(μ4-O) (Mn(aet)3}4]Cl2·MeOH·4H 2O. A complex molecule consists of four fac(S)-[Mn(aet)3] units linked to MnII4(μ4-O) core by thiolato bridges. Magnetic susceptibility measurements revealed the presence of antiferromagnetic interactions through μ4-oxo and μ2-thiolato bridges. Copyright © 2006 The Chemical Society of Japan.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.2006.440
- ISSN : 0366-7022