2003年1月13日
High-spin wheel of a heptanuclear mixed-valent FeII,III complex
Angewandte Chemie - International Edition
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- 巻
- 42
- 号
- 2
- 開始ページ
- 223
- 終了ページ
- 225
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/anie.200390084
Wheels with high spins: The reaction of a tridentate Schiff base ligand with iron (II) chloride, and subsequent oxidation with [(tBu4N) MnO4] yielded a heptanuclear mixed-valent iron wheel (see picture) with a spin ground state of S = 29/2. Cornering the 13th vertex: The first 13-vertex carborane (see picture, B: brown, C: gray, H: white) has been prepared by a methodology that can in principle be applied repeatedly, leading to 14-, 15-, 16-, ... vertex carboranes in the future. The 13-vertex species has a henicosahedral geometry, not the docosahedral one expected, but the two forms are found to be very close in energy by DFT calculations.
- ID情報
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- DOI : 10.1002/anie.200390084
- ISSN : 1433-7851