論文

査読有り
2021年9月

Chemical Complexity of Phosphorous-bearing Species in Various Regions of the Interstellar Medium

ASTRONOMICAL JOURNAL
  • Milan Sil
  • Satyam Srivastav
  • Bratati Bhat
  • Suman Kumar Mondal
  • Prasanta Gorai
  • Rana Ghosh
  • Takashi Shimonishi
  • Sandip K. Chakrabarti
  • Bhalamurugan Sivaraman
  • Amit Pathak
  • Naoki Nakatani
  • Kenji Furuya
  • Ankan Das
  • 全て表示

162
3
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.3847/1538-3881/ac09f9
出版者・発行元
IOP PUBLISHING LTD

Phosphorus-related species are not known to be as omnipresent in space as hydrogen, carbon, nitrogen, oxygen, and sulfur-bearing species. Astronomers spotted very few P-bearing molecules in the interstellar medium and circumstellar envelopes. Limited discovery of the P-bearing species imposes severe constraints in modeling the P-chemistry. In this paper, we carry out extensive chemical models to follow the fate of P-bearing species in diffuse clouds, photon-dominated or photodissociation regions (PDRs), and hot cores/corinos. We notice a curious correlation between the abundances of PO and PN and atomic nitrogen. Since N atoms are more abundant in diffuse clouds and PDRs than in the hot core/corino region, PO/PN reflects <1 in diffuse clouds, MUCH LESS-THAN1 in PDRs, and >1 in the late warm-up evolutionary stage of the hot core/corino regions. During the end of the post-warm-up stage, we obtain PO/PN > 1 for hot core and <1 for its low-mass analog. We employ a radiative transfer model to investigate the transitions of some of the P-bearing species in diffuse cloud and hot core regions and estimate the line profiles. Our study estimates the required integration time to observe these transitions with ground-based and space-based telescopes. We also carry out quantum chemical computation of the infrared features of PH3, along with various impurities. We notice that SO2 overlaps with the PH3 bending-scissoring modes around similar to 1000-1100 cm(-1). We also find that the presence of CO2 can strongly influence the intensity of the stretching modes around similar to 2400 cm(-1) of PH3.

リンク情報
DOI
https://doi.org/10.3847/1538-3881/ac09f9
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000688240400001&DestApp=WOS_CPL
共同研究・競争的資金等の研究課題
計算化学と電波観測の融合によるホットコア化学の研究
ID情報
  • DOI : 10.3847/1538-3881/ac09f9
  • ISSN : 0004-6256
  • eISSN : 1538-3881
  • Web of Science ID : WOS:000688240400001

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