Misc.

Jun, 2016

Synthesis and Photoproperties of Edge-functionalized Zeolite-templated Carbon with Bromine or Carbazole Groups

CHEMISTRY LETTERS
  • Haruko Goto
  • ,
  • Tomoyuki Tajima
  • ,
  • Kazumasa Kobayashi
  • ,
  • Yutaka Takaguchi
  • ,
  • Khanin Nueangnoraj
  • ,
  • Hirotomo Nishihara

Volume
45
Number
6
First page
601
Last page
603
Language
English
Publishing type
DOI
10.1246/cl.160123
Publisher
CHEMICAL SOC JAPAN

We succeeded in synthesizing edge-brominated zeolite-templated carbon (ZTC-Br) as the key intermediate of edge-functionalization of ZTC via an electrophilic aromatic substitution reaction using dibromoisocyanuric acid. ZTC-Br was easily converted into carbazole-modified ZTC (ZTC-Cz) using Suzuki-Miyaura coupling. Interestingly, solvent-dependent changes of the fluorescence intensity of ZTC-Cz owing to its swelling shrinking behavior were observed.

Link information
DOI
https://doi.org/10.1246/cl.160123
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000377152900007&DestApp=WOS_CPL
ID information
  • DOI : 10.1246/cl.160123
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • Web of Science ID : WOS:000377152900007

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