Jun, 2016
Synthesis and Photoproperties of Edge-functionalized Zeolite-templated Carbon with Bromine or Carbazole Groups
CHEMISTRY LETTERS
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- Volume
- 45
- Number
- 6
- First page
- 601
- Last page
- 603
- Language
- English
- Publishing type
- DOI
- 10.1246/cl.160123
- Publisher
- CHEMICAL SOC JAPAN
We succeeded in synthesizing edge-brominated zeolite-templated carbon (ZTC-Br) as the key intermediate of edge-functionalization of ZTC via an electrophilic aromatic substitution reaction using dibromoisocyanuric acid. ZTC-Br was easily converted into carbazole-modified ZTC (ZTC-Cz) using Suzuki-Miyaura coupling. Interestingly, solvent-dependent changes of the fluorescence intensity of ZTC-Cz owing to its swelling shrinking behavior were observed.
- Link information
- ID information
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- DOI : 10.1246/cl.160123
- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000377152900007