2015年5月
Synthesis and Properties of (Terthiophene)(4)-Poly(amidoamine)-C-60 Pentad
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
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- 巻
- 88
- 号
- 5
- 開始ページ
- 736
- 終了ページ
- 745
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/bcsj.20140283
- 出版者・発行元
- CHEMICAL SOC JAPAN
(Terthiophene)(4)-poly(amidoamine)-C-60 pentad 8a and (terthiophene)(2)-poly(amidoamine)-C-60 triad 8b have been synthesized with the aim of developing novel precursors for photoinduced polymerization. The electrochemical oxidation of pentad 8a by repetitive cyclic voltammogram scans gave a polymeric 8a film on a FTO electrode, which showed electrochemical activity and photoelectric response. When a monomer film of 8 on FTO was irradiated with visible light, the photoinduced polymerization of the terthiophene moiety was observed. The photoanodic features of an electropolymerized film of 8a on a FTO (poly-8a(electro)/FTO) and 8a/FTO were investigated regarding photocurrent response to light irradiation. The photocurrent of a photopolymerized 8a film on a FTO (poly-8a(photo)/FTO) electrode formed by photoreaction of 8a/FTO, is approximately 6 times greater than that of the 8a/FTO electrode.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.20140283
- ISSN : 0009-2673
- eISSN : 1348-0634
- Web of Science ID : WOS:000354754200017