2011年
Synthesis of Poly(amidoamine) Dendrimer with a Diphenyl Diselenide Core
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
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- 巻
- 186
- 号
- 1
- 開始ページ
- 2
- 終了ページ
- 11
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1080/10426501003767102
- 出版者・発行元
- TAYLOR & FRANCIS LTD
We succeeded in the synthesis of a novel poly(amidoamine) dendrimer having diphenyl diselenide at the core. Modification of the dendrimer diselenide by the reaction with glucono--lactone in methanol gave a water-soluble dendrimer diselenide having chiral terminal groups. The structures of dendrimers were satisfactorily confirmed by MAIDI-TOF MS spectrometry, elemental analysis, and NMR spectroscopy. Interestingly, induced circular dichroism (ICD) of the interaction between the diphenyl diselenide core and D-gluconamide periphery of the dendrimer was observed at 300 nm. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. GRAPHICAL ABSTRACT[image omitted].
- リンク情報
- ID情報
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- DOI : 10.1080/10426501003767102
- ISSN : 1042-6507
- Web of Science ID : WOS:000286818700002