論文

2016年

Synthesis and characterization of an Ru2(III, IV) complex containing pyrophosphate bridge

Chemistry Letters
  • Yuji Miyazato
  • ,
  • Tohru Wada
  • ,
  • Masaaki Ohba
  • ,
  • Nobuyuki Matsushita

45
12
開始ページ
1388
終了ページ
1390
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/cl.160721
出版者・発行元
Chemical Society of Japan

We prepared a new Ru2(III, IV) complex containing a pyrophosphate as the dinucleating component, by the reaction between the mononuclear complex [Ru(Me3tacn)Cl3] and Na4P2O7�10H2O in aqueous solution. Cyclic voltammetric measurement for the complex [{Ru(Me3tacn)}2(μ-O)(μ-P2O7)]PF6 (1) in aqueous solution revealed the formation of two species with higher oxidation states, such as [O=Ru(IV)Ru(IV)=O] and [O=Ru(IV)Ru(V)=O]+. Furthermore, this complex showed activity for water oxidation reaction with Ce(NH4)2(NO3)6 as the chemical oxidant in acidic aqueous solution.

リンク情報
DOI
https://doi.org/10.1246/cl.160721
ID情報
  • DOI : 10.1246/cl.160721
  • ISSN : 1348-0715
  • ISSN : 0366-7022
  • SCOPUS ID : 84996606915

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