2017年1月
Substrate Binding by a Parallel Metal Sheet Sandwich Complex: A Unique Role of an Additional Metal Atom
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- ,
- ,
- 巻
- 56
- 号
- 5
- 開始ページ
- 1346
- 終了ページ
- 1350
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/anie.201610784
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
A unique metal addition to the edge of a triangular palladium sandwich cluster is reported. While the edge coordination sites of a parallel sandwich complex are narrow because of two sterically encumbering pi-ligands, association of an additional metal atom to a metal sheet gives a wider coordination site. It was proved that the additional metal atom plays a crucial role in binding of cyclopentadienyl by a Pd-3 sheet sandwich complex.
- リンク情報
- ID情報
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- DOI : 10.1002/anie.201610784
- ISSN : 1433-7851
- eISSN : 1521-3773
- Web of Science ID : WOS:000394997700030