論文

査読有り
2013年

Cobalt porphyrins as homogeneous catalysts for water oxidation

CHEMICAL COMMUNICATIONS
  • Takashi Nakazono
  • ,
  • Alexander Rene Parent
  • ,
  • Ken Sakai

49
56
開始ページ
6325
終了ページ
6327
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c3cc43031f
出版者・発行元
ROYAL SOC CHEMISTRY

Three water-soluble cobalt porphyrins have been investigated as water oxidation catalysts via photo-initiation using Ru-II(bpy)(3)(2+)/Na2S2O8. The pH dependence of the turnover frequency revealed maximum activity at pH 11. Based on the second order dependence on catalyst concentration for the rate of water oxidation, we suggest a bimolecular radical coupling process as the rate determining step.

Web of Science ® 被引用回数 : 183

リンク情報
DOI
https://doi.org/10.1039/c3cc43031f
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000320555800025&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/c3cc43031f
  • ISSN : 1359-7345
  • Web of Science ID : WOS:000320555800025

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