Papers

Peer-reviewed
Aug, 2016

Improving the robustness of cobalt porphyrin water oxidation catalysts by chlorination of aryl groups

DALTON TRANSACTIONS
  • Takashi Nakazono
  • ,
  • Ken Sakai

Volume
45
Number
32
First page
12649
Last page
12652
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1039/c6dt02535h
Publisher
ROYAL SOC CHEMISTRY

The water oxidation (WO) activity of a chlorinated cobalt tetraphenylporphyrin (CoClPS), possessing Cl atoms on the 2,6-positions of the aryl groups, shows higher resistance to attack by singlet oxygen, in situ generated during photochemical WO using Ru(bpy)(3)(2+) and S2O82- with the turnover frequency (TOF) and turnover number (TON) reaching 1.7 s(-1) and 836, respectively.

Web of Science ® Times Cited Count : 16
View Related Records® in Web of Science ®

Link information
DOI
https://doi.org/10.1039/c6dt02535h
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000381478500007&DestApp=WOS_CPL
ID information
  • DOI : 10.1039/c6dt02535h
  • ISSN : 1477-9226
  • eISSN : 1477-9234
  • Web of Science ID : WOS:000381478500007

Export
BibTeX RIS