論文

査読有り
2016年8月

Improving the robustness of cobalt porphyrin water oxidation catalysts by chlorination of aryl groups

DALTON TRANSACTIONS
  • Takashi Nakazono
  • ,
  • Ken Sakai

45
32
開始ページ
12649
終了ページ
12652
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c6dt02535h
出版者・発行元
ROYAL SOC CHEMISTRY

The water oxidation (WO) activity of a chlorinated cobalt tetraphenylporphyrin (CoClPS), possessing Cl atoms on the 2,6-positions of the aryl groups, shows higher resistance to attack by singlet oxygen, in situ generated during photochemical WO using Ru(bpy)(3)(2+) and S2O82- with the turnover frequency (TOF) and turnover number (TON) reaching 1.7 s(-1) and 836, respectively.

Web of Science ® 被引用回数 : 15

リンク情報
DOI
https://doi.org/10.1039/c6dt02535h
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000381478500007&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/c6dt02535h
  • ISSN : 1477-9226
  • eISSN : 1477-9234
  • Web of Science ID : WOS:000381478500007

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