Papers

Peer-reviewed
Oct, 2016

Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex

CHEMPLUSCHEM
  • Ryota Terao
  • ,
  • Takashi Nakazono
  • ,
  • Alexander Rene Parent
  • ,
  • Ken Sakai

Volume
81
Number
10
First page
1064
Last page
1067
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1002/cplu.201600263
Publisher
WILEY-V C H VERLAG GMBH

Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O-O bond formation.

Web of Science ® Times Cited Count : 41
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Link information
DOI
https://doi.org/10.1002/cplu.201600263
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000386078200007&DestApp=WOS_CPL
ID information
  • DOI : 10.1002/cplu.201600263
  • ISSN : 2192-6506
  • Web of Science ID : WOS:000386078200007

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