2015年
A dense La(Sr)Fe(Mn)O<inf>3-δ</inf> nano-film anode for intermediate-temperature solid oxide fuel cells
Journal of Materials Chemistry A
- ,
- ,
- ,
- ,
- 巻
- 3
- 号
- 7
- 開始ページ
- 3586
- 終了ページ
- 3593
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c4ta05664g
? The Royal Society of Chemistry 2015. To achieve high power density in intermediate-temperature solid oxide fuel cells (IT-SOFCs), we introduce a dense La(Sr)Fe(Mn)O3-δ (LSFM) nano-film anode between a Ni-Fe metallic substrate and a LaGaO3-based oxide electrolyte. Although a three-phase boundary (TPB) is believed to be required for anode active sites, the cell with the LSFM mixed-conductor thin-film anode exhibited much improved power density compared with that of the cell with a simple porous Ni-Fe anode. The maximum power density of the cell with the LSFM film was approximately 3.0 W cm-2 at 973 K. The improved power density was primarily attributed to the enhanced anodic activity. Furthermore, we observed that the dense LSFM thin-film anode is effective in increasing the fuel utilization of a Ni-Fe metallic anode supported cell. This suggests that a two-phase boundary (anode and gas phase) at the LaFeO3 perovskite is highly active towards the anodic reaction.
- リンク情報
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- DOI
- https://doi.org/10.1039/c4ta05664g
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000349447200044&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84922791397&origin=inward
- ID情報
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- DOI : 10.1039/c4ta05664g
- ISSN : 2050-7488
- eISSN : 2050-7496
- Web of Science ID : WOS:000349447200044