論文

2002年7月

Reactivity of the hydrogen atoms on diamond surface with various radical initiators in mild condition

DIAMOND AND RELATED MATERIALS
  • T Tsubota
  • ,
  • O Hirabayashi
  • ,
  • S Ida
  • ,
  • S Nagaoka
  • ,
  • M Nagata
  • ,
  • Y Matsumoto

11
7
開始ページ
1360
終了ページ
1365
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/S0925-9635(01)00742-7
出版者・発行元
ELSEVIER SCIENCE SA

Radical reactions of various radical initiators in liquid phase were carried out to investigate the reactivity of hydrogenated diamond surface. Benzophenone, which is one of the most popular photosensitizers, and AIBN (alpha,alpha'-azobisisobutyronitrile), which is one of the most popular radical initiators of azo compounds, could not abstract hydrogen atoms on the diamond surface. On the other hand, benzoyl peroxide, which is one of the most popular radical initiators of peroxides, could abstract the hydrogen atoms on a diamond surface. From the results of this study, it was found that the reactivity for the hydrogen abstraction reaction with organic radical reagents depends on the kind of the radical species. (C) 2002 Elsevier Science B.V. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/S0925-9635(01)00742-7
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000176218800007&DestApp=WOS_CPL
URL
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0036645273&origin=inward
ID情報
  • DOI : 10.1016/S0925-9635(01)00742-7
  • ISSN : 0925-9635
  • Web of Science ID : WOS:000176218800007

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