論文

2001年

Hydrogen abstraction reaction of hydrogenated diamond surface in liquid phase by radical initiators used in polymer synthesis

Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
  • Toshiki Tsubota
  • ,
  • Osamu Hirabayashi
  • ,
  • Shintaro Ida
  • ,
  • Shoji Nagaoka
  • ,
  • Masanori Nagata
  • ,
  • Yasumichi Matsumoto
  • ,
  • Katsuki Kusakabe
  • ,
  • Shigeharu Morooka

2001
11
開始ページ
631
終了ページ
636
記述言語
日本語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/nikkashi.2001.631
出版者・発行元
Chemical Society of Japan

Various radical initiators were used for investigating the hydrogen abstraction reaction on hydrogenated diamond surface. Benzophenone excited by UV light, which is one of the most popular photosensitizers, could not abstract the hydrogen atoms. Thermally excited α,α′-azobisisobutyronitrile (AIBN), which is one of the most popular radical initiators of azo compounds, could also not abstract the hydrogen atoms. On the other hand, benzoyl peroxide, which is one of the most popular radical initiators of peroxide compounds, could abstract the hydrogen atoms. The reaction rate of the hydrogen abstraction reaction by benzoyl peroxide depended on the species of solvent. The hydrogen atoms in CH2 group on (100) face are more reactive than that in CH3 group on (111) face.

リンク情報
DOI
https://doi.org/10.1246/nikkashi.2001.631
URL
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0010071609&origin=inward
ID情報
  • DOI : 10.1246/nikkashi.2001.631
  • ISSN : 0369-4577
  • SCOPUS ID : 0010071609

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