論文

査読有り
2017年

Deep melting reveals liquid structural memory and anomalous ferromagnetism in bismuth

Proceedings of the National Academy of Sciences of the United States of America
  • Shu, Y.
  • ,
  • Yu, D.
  • ,
  • Hu, W.
  • ,
  • Wang, Y.
  • ,
  • Shen, G.
  • ,
  • Kono, Y.
  • ,
  • Xu, B.
  • ,
  • He, J.
  • ,
  • Liu, Z.
  • ,
  • Tian, Y.

114
13
開始ページ
3375
終了ページ
3380
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1073/pnas.1615874114
出版者・発行元
NATL ACAD SCIENCES

As an archetypal semimetal with complex and anisotropic Fermi surface and unusual electric properties (e.g., high electrical resistance, large magnetoresistance, and giant Hall effect), bismuth (Bi) has played a critical role in metal physics. In general, Bi displays diamagnetism with a high volumetric susceptibility (similar to 10(-4)). Here, we report unusual ferromagnetism in bulk Bi samples recovered from a molten state at pressures of 1.4-2.5 GPa and temperatures above similar to 1,250 K. The ferromagnetism is associated with a surprising structural memory effect in the molten state. On heating, low-temperature Bi liquid (L) transforms to a more randomly disordered high-temperature liquid (L') around 1,250 K. By cooling from above 1,250 K, certain structural characteristics of liquid L' are preserved in L. Bi clusters with characteristics of the liquid L' motifs are further preserved through solidification into the Bi-II phase across the pressure-independent melting curve, which may be responsible for the observed ferromagnetism.

リンク情報
DOI
https://doi.org/10.1073/pnas.1615874114
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/28289195
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000397607300056&DestApp=WOS_CPL
Scopus Url
http://www.scopus.com/inward/record.url?eid=2-s2.0-85016425324&partnerID=MN8TOARS 本文へのリンクあり
URL
http://orcid.org/0000-0001-5916-7524
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85016425324&origin=inward
ID情報
  • DOI : 10.1073/pnas.1615874114
  • ISSN : 0027-8424
  • eISSN : 1091-6490
  • ORCIDのPut Code : 34976351
  • PubMed ID : 28289195
  • SCOPUS ID : 85016425324
  • Web of Science ID : WOS:000397607300056

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